Three-phase polymer composites are promising materials for creating electronic device components. The qualitative and quantitative composition of such composites has a significant effect on their functional, in particular dielectric properties. In this study, ceramic filler K 2 Ni 0.93 Ti 7.07 O 16 (KNTO) with Ag coating as conductive additive (0.5, 1.0, 2.5 wt.%) was introduced into the polyvinylidene difluoride (PVDF) polymer matrix in amounts of 7.5, 15, 22.5, and 30 vol.%. to optimize the dielectric constant and dielectric loss tangent. The filler was characterized by X-ray phase analysis, Fourier-transform infrared spectroscopy and Scanning electron microscopy methods. The dielectric constant, dielectric loss tangent, and conductivity of three-phase composites KNTO@Ag-PVDF were studied in comparison with two-phase composites KNTO-PVDF in the frequency range from 10 2 Hz to 10 6 Hz. The dielectric constant values of composites containing 7.5, 15, 22.5, and 30 vol.% filler were 12, 13, 17.4, 19.2 for pure KNTO and 13, 19, 25, 31 for KNTO@Ag filler (2.5 wt.%) at frequency 10 kHz. The dielectric loss tangent ranged from 0.111 to 0.340 at a filler content of 7.5 to 30 vol.%. A significantly enhanced balance of dielectric properties of PVDF-based composites was found with K 2 Ni 0.93 Ti 7.07 O 16 as ceramic filler for 1 wt.% of silver. Composites KNTO@Ag(1 wt.%)-PVDF can be applied as dielectrics for passive elements of flexible electronics.