Abstract This manuscript explores the potential of macro-X-ray fluorescence (MA-XRF) for the non-invasive analysis of heritage textiles. XRF, especially with the portable instruments, is a well-known technique for the non-destructive examination of various cultural heritage objects. It allows analysis of elemental composition based on single-point measurements. However, large, or complex textiles require numerous analysis points to identify the materials used and correctly interpret the spectra. MA-XRF takes this type of research to the next level, as it is possible to visualise the element distribution over an entire mapped area. In this paper, we discuss the application of this technique to the study of complex and multi-layered textile objects from exceptional Belgian heritage collections, including two mitres attributed to Bishop Jacques de Vitry, dating between twelfth and thirteenth century, and two of the seven extremely fine medieval reliquary purses from Namur. These are very fragile, richly ...