Contamination sources of PCDD/Fs, non-ortho PCBs and PAHs in sediments of high and low impacted transboundary rivers (Belgium-France)

International audience ; PAHs, PCDD/Fs and non-ortho PCBs have been assessed in Yser and Upper-Scheldt river sediments. Higher contamination levels were observed in the Upper-Scheldt sediments: maximum concentrations for the 16 US-EPA PAHs, PCDD/Fs and non-ortho PCBs respectively amount to 8.9mgkg -1, 12ng TEQkg -1 and 5.1ng TEQkg -1. Diagnostic PAH ratios in sediments and atmospheric samples suggest that the PAH compounds are from pyrolytic origin, more specifically combustion processes. The huge consumption of coal in cokes-ovens and smelters and its use for house-heating in Northern France,... Mehr ...

Verfasser: Sanctorum, Hermes
Elskens, Marc
Leermakers, Martine
Gao, Yue
Charriau, Adeline
Billon, Gabriel
Goscinny, Séverine
de Cooman, Ward
Baeyens, Willy
Dokumenttyp: Artikel
Erscheinungsdatum: 2011
Verlag/Hrsg.: HAL CCSD
Schlagwörter: PAHs / PCDD/F / Non-ortho PCB / Sediments / Upper-Scheldt river / Yser river / [CHIM.ANAL]Chemical Sciences/Analytical chemistry / [SDE.IE]Environmental Sciences/Environmental Engineering
Sprache: Englisch
Permalink: https://search.fid-benelux.de/Record/base-29362903
Datenquelle: BASE; Originalkatalog
Powered By: BASE
Link(s) : https://hal.science/hal-00922202

International audience ; PAHs, PCDD/Fs and non-ortho PCBs have been assessed in Yser and Upper-Scheldt river sediments. Higher contamination levels were observed in the Upper-Scheldt sediments: maximum concentrations for the 16 US-EPA PAHs, PCDD/Fs and non-ortho PCBs respectively amount to 8.9mgkg -1, 12ng TEQkg -1 and 5.1ng TEQkg -1. Diagnostic PAH ratios in sediments and atmospheric samples suggest that the PAH compounds are from pyrolytic origin, more specifically combustion processes. The huge consumption of coal in cokes-ovens and smelters and its use for house-heating in Northern France, although decreasing during the last decades, are in support of that suggestion. PCDD/F fingerprints in sediments and deposition material indicate that OCDD is the dominant congener. In addition use of pentachlorophenol (PCP) in the past led to a minor contribution of PCDD/Fs in our sediment samples. Non-ortho PCBs form a substantial fraction of the total TEQ concentrations observed in the sediments. Since the 1980s and 1990s a substantial reduction of the PCDD/F sediment concentrations is observed, but this is not the case for the PAHs.