Transient SSITKA-DRIFTS Spectra of Photo-assisted Sabatier Reaction on La promoted NiOx Catalysts ...
Herein, we isolate the rate-determining intermediate species in the photo-assisted Sabatier reaction on La promoted NiO x /TiO 2 by in-situ isotopic spectroscopy. Specifically, adsorbed intermediate species formed during the photo-assisted Sabatier reaction were directly probed using Steady-State Isotopic Kinetic Analysis coupled with Diffuse Reflectance Infrared Fourier Transform Spectroscopy (SSITKA-DRIFTS). The photo-activation of the formate adsorbate (HCO 2 *) offers an eight-fold photo-enhancement on NiO x /La 2 O 3 @TiO 2 . ...
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| Dokumenttyp: | Journal contribution |
| Erscheinungsdatum: | 2020 |
| Verlag/Hrsg.: |
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| Schlagwörter: | 90402 Catalytic Process Engineering / FOS: Chemical engineering / 91202 Composite and Hybrid Materials / FOS: Materials engineering / 91305 Energy Generation / Conversion and Storage Engineering / FOS: Mechanical engineering / 90406 Powder and Particle Technology / 90608 Renewable Power and Energy Systems Engineering excl. Solar Cells / FOS: Electrical engineering / electronic engineering / information engineering / 90401 Carbon Capture Engineering excl. Sequestration / 90403 Chemical Engineering Design |
| Sprache: | unknown |
| Permalink: | https://search.fid-benelux.de/Record/base-29233118 |
| Datenquelle: | BASE; Originalkatalog |
| Powered By: | BASE |
| Link(s) : | https://dx.doi.org/10.6084/m9.figshare.13003940.v1 |
