High Resolution Spectroscopy of CF3Br by Diode Laser in the Frequency Range 1070–1090 cm−1
The IR absorption spectra of gaseous CF3Br expanded in a molecular jet have been recorded with a linewidth of about 0.002 cm−1. The rotational K-structure of the ν1 fundamental has been resolved and the molecular constants ΔB and ΔA have been determined with an accuracy better than 5 x 10−6 cm−1. Spectral features belonging to the ν6- and ν3-hotbands have been identified. For CF3B79r (CF3B81r) improved values of the vibrational origins for the fundamental ν1 = 1084.768(2) cm−1 (1084.520(2) cm−1) and for its hotbands ν3+ν1←ν3 = 1081.709(80) cm−1 (1081.065(40) cm−1) and ν6+ν1←ν6 = 1083.533(4) cm... Mehr ...
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Dokumenttyp: | Artikel |
Erscheinungsdatum: | 1988 |
Schlagwörter: | Netherlands / Spectroscopy / Biochemistry / Atomic and Molecular Physics / and Optics |
Sprache: | Englisch |
Permalink: | https://search.fid-benelux.de/Record/base-29181163 |
Datenquelle: | BASE; Originalkatalog |
Powered By: | BASE |
Link(s) : | https://www.openaccessrepository.it/record/106195 |
The IR absorption spectra of gaseous CF3Br expanded in a molecular jet have been recorded with a linewidth of about 0.002 cm−1. The rotational K-structure of the ν1 fundamental has been resolved and the molecular constants ΔB and ΔA have been determined with an accuracy better than 5 x 10−6 cm−1. Spectral features belonging to the ν6- and ν3-hotbands have been identified. For CF3B79r (CF3B81r) improved values of the vibrational origins for the fundamental ν1 = 1084.768(2) cm−1 (1084.520(2) cm−1) and for its hotbands ν3+ν1←ν3 = 1081.709(80) cm−1 (1081.065(40) cm−1) and ν6+ν1←ν6 = 1083.533(4) cm-1 (1083.288(4) cm-1) have been determined.