Both public policy-makers and private companies promote carpooling as a commuting alternative in order to reduce the number of Single Occupant Vehicle (SOV) users. The Belgian questionnaire Home-To-Work-Travel (HTWT) is used to examine the factors which explain the share of carpooling employees at a worksite. The modal split between carpooling and rail use was also subject of the analysis. The number of observations in the HTWT database (n=7460) makes it possible to use more advanced statistical models: such as multilevel regression models which incorporate, next to the worksite level, also the company and economic sector levels. As a consequence, a more employer-oriented approach replaces the traditional focus of commuting research on the individual. Significant differences in modal split between economic sectors appeared. The most carpool-oriented sectors are construction and manufacturing, while rail transport is more popular in the financial and public sector. Carpooling also tend to be an alternative at locations where rail is no real alternative. Next to this, regular work schedules and smaller sites are positively correlated with a higher share of carpooling employees. Finally, no real evidence could be found for the effectiveness of mobility management measures which promote carpooling. However, most of these measures are classified in the literature as less effective and a case study approach should complete the research on mobility management initiatives.