The Sabatier reaction could be a key tool for the future of the renewable energy field due to the potential of this reaction to produce either fuels or to stabilize H 2 in the form of stable chemicals. For this purpose, a new composite made of ruthenium oxide nanoparticles (NPs) deposited on titanate nanotubes (TiNTs) was tested. Titanate nanotubes are a robust semiconductor with a one-dimensional (1D) morphology that results in a high contact area making this material suitable for photocatalysis. Small ruthenium nanoparticles (1.5 nm) were deposited on TiNTs at different ratios by Na + -to-Ru 3+ ion exchanges followed by calcination. These samples were tested varying light power and temperature conditions to study the reaction mechanism during catalysis. Methanation of CO 2 catalyzed by Ru/TiNT composite exhibit photonic and thermic contributions, and their ratios vary with temperature and light intensity. The synthesized composite achieved a production rate of 12.4 mmol CH 4 ·g cat −1 ·h −1 equivalent to 110.7 mmol of CH 4 ·g Ru −1 ·h −1 under 150 mW/cm 2 simulated sunlight irradiation at 210 °C. It was found that photo-response derives either from Ru nanoparticle excitation in the visible (VIS) and near-infrared (NIR) region (photothermal and plasmon excitation mechanism) or from TiNT excitation in the ultraviolet (UV) region leading to electron–hole separation and photoinduced electron transfer.