Long-chain diols and BIT index in surface sediments and cores GeoB7702-3 and 64PE304-80

The study of past sedimentary records from coastal margins allows us to reconstruct variations in terrestrial input into the marine realm and to gain insight into continental climatic variability. There are numerous organic proxies for tracing terrestrial input into marine environments but none that strictly reflect the input of river-produced organic matter. Here, we test the fractional abundance of the C32 alkane 1,15-diol relative to all 1,13- and 1,15-long-chain diols (FC32 1, 15) as a tracer of input of river-produced organic matter in the marine realm in surface and Quaternary (0-45 ka)... Mehr ...

Verfasser: Lattaud, Julie
Dorhout, Denise J C
Schulz, Hartmut
Castañeda, Isla S
Schefuß, Enno
Sinninghe Damsté, Jaap S
Schouten, Stefan
Dokumenttyp: Dataset
Erscheinungsdatum: 2017
Verlag/Hrsg.: PANGAEA
Schlagwörter: NIOZ_UU / NIOZ Royal Netherlands Institute for Sea Research / and Utrecht University
Sprache: Englisch
Permalink: https://search.fid-benelux.de/Record/base-27201712
Datenquelle: BASE; Originalkatalog
Powered By: BASE
Link(s) : https://doi.pangaea.de/10.1594/PANGAEA.879796

The study of past sedimentary records from coastal margins allows us to reconstruct variations in terrestrial input into the marine realm and to gain insight into continental climatic variability. There are numerous organic proxies for tracing terrestrial input into marine environments but none that strictly reflect the input of river-produced organic matter. Here, we test the fractional abundance of the C32 alkane 1,15-diol relative to all 1,13- and 1,15-long-chain diols (FC32 1, 15) as a tracer of input of river-produced organic matter in the marine realm in surface and Quaternary (0-45 ka) sediments on the shelf off the Zambezi and nearby smaller rivers in the Mozambique Channel (western Indian Ocean). A Quaternary (0-22 ka) sediment record off the Nile River mouth in the eastern Mediterranean was also studied for long-chain diols. For the Mozambique Channel, surface sediments of sites most proximal to Mozambique rivers showed the highest F1, 15 - C32 (up to 10 k%). The sedimentary record shows high (15-35 k%) pre-Holocene F1, 15 - C32 and low (< 10 k%) Holocene F1, 15 - C32 values, with a major decrease between 18 and 12 ka. F1, 15 - C32 is significantly correlated (r2 = 0.83, p < 0.001) with the branched and isoprenoid tetraether (BIT) index, a proxy for the input of soil and river-produced organic matter in the marine environment, which declines from 0.25 to 0.60 for the pre-Holocene to < 0.10 for the Holocene. This decrease in both FC32 1, 15 and the BIT is interpreted to be mainly due to rising sea level, which caused the Zambezi River mouth to become more distal to our study site, thereby decreasing riverine input at the core location. Some small discrepancies are observed between the records of the BIT index and FC32 1, 15 for Heinrich Event 1 (H1) and the Younger Dryas (YD), which may be explained by a change in soil sources in the catchment area rather than a change in river influx. Like for the Mozambique Channel, a significant correlation between FC32 1, 15 and the BIT index (r2 = 0.38, p ...