Enhancing Oxygen Evolution Reaction Activity by Using Switchable Polarization in Ferroelectric InSnO 2 N

Ferroelectric modulation of the surface charge density is a promising strategy to promote the surface oxygen evolution reaction (OER) in photocatalytic water splitting. The limitations of the Sabatier principle could be overcome by tuning the interaction strength between the OER intermediates and the surface for the individual reaction steps via switching of the polarization direction. InSnO 2 N, a newly reported improper ferroelectric semiconductor, is promising for applications as a photocatalyst due to its direct band gap of 1.61 eV and its sizable ferroelectric polarization. Therefore, in... Mehr ...

Verfasser: Zhenyun Lan (4976873)
Didrik René Småbråten (11512207)
Chengcheng Xiao (10277649)
Tejs Vegge (1262904)
Ulrich Aschauer (2885759)
Ivano E. Castelli (3836215)
Dokumenttyp: Text
Erscheinungsdatum: 2021
Schlagwörter: Biophysics / Medicine / Evolutionary Biology / Infectious Diseases / Chemical Sciences not elsewhere classified / Physical Sciences not elsewhere classified / sabatier principle could / relevant frequency range / polarized bulk structure / photocatalytic water splitting / direct band gap / 6 – 12 / using switchable polarization / 77 v ) / 58 v versus / 37 v ) / sizable ferroelectric polarization / bulk polarization direction / surface charge density / reaction free energy / negatively polarized bulk / highly promising route / n ferroelectric modulation / lower theoretical overpotential / 3 ml oh / 2 </ sub / polarization direction / theoretical overpotential / 89 v / 23 v / 20 v / polarization switching / ferroelectric switching / surface covered / study demonstrates / promising strategy / photocatalyst due / overpotential becomes / oh coverage / interaction strength / improper ferroelectricity / ferroelectric insno / energetic cost / covered surface / clean surface / also showing / 61 ev
Sprache: unknown
Permalink: https://search.fid-benelux.de/Record/base-26870740
Datenquelle: BASE; Originalkatalog
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Link(s) : https://doi.org/10.1021/acscatal.1c03737.s001