Impact of Geometric and Electronic Factors on Selective Hydro-Deoxygenation of Guaiacol by Surface-Rich Metal/Silica Catalysts
The selective production of hydrocarbons for the chemical industry from biogenic feedstock is a significant challenge when ensuring hydrocarbon and fuel supply, despite the heterogeneity of this feed. In this study, guaiacol, as a surrogate for complex lignin-based biomass resources, is converted by an inert silica carrier material with different d-metal impregnation (Mo, W, Re, Fe, Co, Ni, Cu, Pd, Ag) to reveal the reasons for different product selectivity to hydrogenated and deoxygenated hydrocarbon products. Hydrogen at 15 bar (gauge) and guaiacol are converted on metal/silica catalysts bet... Mehr ...
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Dokumenttyp: | Text |
Erscheinungsdatum: | 2023 |
Verlag/Hrsg.: |
Multidisciplinary Digital Publishing Institute
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Schlagwörter: | hydrodeoxygenation / guaiacol / sabatier’s principle / electronic correspondence / geometric correspondence / oxophilicity / volcano plot / pseudo van Krevelen diagram |
Sprache: | Englisch |
Permalink: | https://search.fid-benelux.de/Record/base-26867125 |
Datenquelle: | BASE; Originalkatalog |
Powered By: | BASE |
Link(s) : | https://doi.org/10.3390/catal13020425 |