Long-term halocarbon observations from a coastal and an inland site in Sabah, Malaysian Borneo

Short-lived halocarbons are believed to have important sources in the tropics, where rapid vertical transport could provide a significant source to the stratosphere. In this study, quasi-continuous measurements of short-lived halocarbons are reported for two tropical sites in Sabah (Malaysian Borneo), one coastal and one inland (rainforest). We present the observations for C 2 Cl 4 , CHBr 3 , CH 2 Br 2 * (actually ~80% CH 2 Br 2 and ~20% CHBrCl 2 ) and CH 3 I from November 2008 to January 2010 made using our μDirac gas chromatographs with electron capture detection (GC-ECD). We focus on the fi... Mehr ...

Verfasser: A. D. Robinson
N. R. P. Harris
M. J. Ashfold
B. Gostlow
N. J. Warwick
L. M. O'Brien
E. J. Beardmore
M. S. M. Nadzir
S. M. Phang
A. A. Samah
S. Ong
H. E. Ung
L. K. Peng
S. E. Yong
M. Mohamad
J. A. Pyle
Dokumenttyp: Artikel
Erscheinungsdatum: 2014
Reihe/Periodikum: Atmospheric Chemistry and Physics, Vol 14, Iss 16, Pp 8369-8388 (2014)
Verlag/Hrsg.: Copernicus Publications
Schlagwörter: Physics / QC1-999 / Chemistry / QD1-999
Sprache: Englisch
Permalink: https://search.fid-benelux.de/Record/base-26862291
Datenquelle: BASE; Originalkatalog
Powered By: BASE
Link(s) : https://doi.org/10.5194/acp-14-8369-2014

Short-lived halocarbons are believed to have important sources in the tropics, where rapid vertical transport could provide a significant source to the stratosphere. In this study, quasi-continuous measurements of short-lived halocarbons are reported for two tropical sites in Sabah (Malaysian Borneo), one coastal and one inland (rainforest). We present the observations for C 2 Cl 4 , CHBr 3 , CH 2 Br 2 * (actually ~80% CH 2 Br 2 and ~20% CHBrCl 2 ) and CH 3 I from November 2008 to January 2010 made using our μDirac gas chromatographs with electron capture detection (GC-ECD). We focus on the first 15 months of observations, showing over one annual cycle for each compound and therefore adding significantly to the few limited-duration observational studies that have been conducted thus far in southeast Asia. The main feature in the C 2 Cl 4 behaviour at both sites is its annual cycle, with the winter months being influenced by northerly flow with higher concentrations, typical of the Northern Hemisphere, and with the summer months influenced by southerly flow and lower concentrations representative of the Southern Hemisphere. No such clear annual cycle is seen for CHBr 3 , CH 2 Br 2 * or CH 3 I. The baseline values for CHBr 3 and CH 2 Br 2 * are similar at the coastal (overall median: CHBr 3 1.7 ppt, CH 2 Br 2 * 1.4 ppt) and inland sites (CHBr 3 1.6 ppt, CH 2 Br 2 * 1.1 ppt), but periods with elevated values are seen at the coast (overall 95th percentile: CHBr 3 4.4 ppt, CH 2 Br 2 ast 1.9 ppt), presumably resulting from the stronger influence of coastal emissions. Overall median bromine values from [CHBr 3 × 3] + [CH 2 Br 2 * × 2] are 8.0 ppt at the coast and 6.8 ppt inland. The median values reported here are largely consistent with other limited tropical data and imply that southeast Asia generally is not, as has been suggested, a hot spot for emissions of these compounds. These baseline values are consistent with the most recent emissions found for southeast Asia using the p-TOMCAT (Toulouse Off-line Model of ...