We present net emission estimates of CH 4 and N 2 O of The Netherlands based on measurements conducted during the period of May 2006 to April 2009 at station Lutjewad, The Netherlands (6°21' E, 53°24' N, 1 m a.s.l.). 222 Radon mixing ratios were applied as an indicator for vertical mixing and long-range air mass transport and used to calculate the net surface fluxes from atmospheric mixing ratios of CH 4 and N 2 O. Our study shows that our measurement site Lutjewad is well-suited to measure emissions from The Netherlands and validation of the national inventories using the 222 Radon flux method. Since this study is purely observation-based it is independent from inventories or atmospheric models. Our results are compared to the national inventories as reported to the UNFCCC. We found net emissions of: (15.2±5.3) t km −2 a −1 for CH 4 and (0.9±0.3) t km −2 a −1 for N 2 O. These values are lower than the inventory-based emissions (2006-2008 averages) of (18.3±3.3) t km −2 a −1 for CH 4 , and (1.3±0.6) t km −2 a −1 for N 2 O, but the differences are insignificant.